A. de Cózar Group
2014
(46) Regio and diastereoselective multicomponent 1,3-dipolar cycloadditions between prolinate
hydrochlorides, aldehydes and dipolarophiles for the direct synthesis of pyrrolizidines
Juan Mancebo-Aracil, Carmen Nájera,* Luis M. Castelló, José M. Sansano,* Olatz Larrañaga, Abel de Cózar,
Fernando P. Cossío
Tetrahedron 2015, 71, 9645–9661.
(45) Resonance driven regioselective demethylation of berberine. Microwave assisted synthesis of
berberrubine and its assessment as fluorescent chemosensor for alkanes
Arantzazu Delgado-Camón, Carmen Jarne, Vicente L. Cebolla,* Olatz Larrañaga, Abel de Cózar, Fernando P.
Cossío, Yosu Vara, Andrés Domñinguez, Luis Membrado, Javier Galbán, Rosa Garriga
Tetrahedron 2015, 71, 6148–6154.
(44) Enantioselective Synthesis of exo-4-Nitroprolinates from Nitro- alkenes and Azomethine Ylides Catalyzed by
Chiral Phosphor- amidite·Silver(I) or Copper(II) Complexes
Luis M. Castelló, Carmen Nájera, José M. Sansano,* Olatz Larrañaga, Abel de Cózar, Fernando P. Cossío
(43) Synthesis of Chromen[4,3-b]pyrrolidines by Intramolecular 1,3-Dipolar Cycloadditions of Azomethine
Ylides: An Experimental and Computational Assessment of the Origin of Stereocontrol
Paulo R. R. Costa, José M. Sansano,* Unai Cossío, Julio, C. F. Barcellos, Ayres G. Días, Carmen Nájera, Ana
Arrieta, Abel de Cózar, Fernando P. Cossío*
Eur. J. Org. Chem. 2015, 4689–4698.
(42) Remote Substituent Effects on the Stereoselectivity and Organocatalytic Activity of Densely Substituted
Unnatural Proline Esters in Aldol Reactions
María de G. Retamosa, Abel de Cózar, Mirian Sánchez, José I. Miranda, José M. Sansano, Luis M. Castelló,
Carmen Nájera, Ana I. Jiménez, Francisco J. Sayago, Carlos Cativiela, Fernando P. Cossío*,
Eur. J. Org. Chem. 2015, 2503–2516.
(41) Azobenzene-functionalized iridium(III) triscyclometalated complexes
Jorge Pérez-Miqueo, Ainara Telleira, Martín Muñoz-Olasagasti, Ainhoa Altube, Eva García-Lecina, Abel de Cózar,
Zoraida Freixa*
Dalton Trans. 2015, 44, 2075–2091.
(40) Synthesis of radiolabelled aryl azides from diazonium salts: experimental and computational results
permit the identification of the preferred mechanism
Sarmeer M. Joshi, Abel de Cózar, Vanessa Gómez-Vallejo, Jacek Koziorowski, Jordi Llop,* Fernando P. Cossío*
Chem. Commun. 2015, 51, 8954–8957.
(39) Is it possible to achieve a complete desaturation of cycloalkanes promoted by o-benzyne?
Francisco Cervantes-Navarro, Abel de Cózar, Fernando P. Cossío,* María A. Fernandez-Herrera, Gabriel Merino,*
Israel Fernandez*
Chem. Commun. 2015, 51, 5302–5305.
(38) Azobenzene-Appended Bis-Cyclometalated Iridium(III) Bipyridyl Complexes
Ainara Telleira, Jorge Pérez-Miqueo, Ainhoa Altube, Eva García-Lecina, Abel de Cózar, Zoraida Freixa*
Organometallics 2015, 34, 5513–5529.
2015
(54) Taniaphos AgF-catalyzed enantioselective 1,3-dipolar cycloaddition of stabilized azomethine ylides
derived from 2,2-dimethoxyacetaldehyde
Alberto Cayuelas, Olatz Larrañaga, Carmen Nájera, José M. Sansano,* Abel de Cózar, Fernando P.
Cossío*
Tetrahedron 2016, 72, 6043–6051.
(53) Cyclopropanation reactions catalysed by dendrimers possessing one metalloporphyrin active site at the
core: linear and sigmoidal kinetic behaviour for different dendrimer generations
Petr Vins, Abel de Cózar, Iván Rivilla, Katerina Novakova, Ronen Zangi, Josef Cvackz, Iosune Arrastia, Ana
Arrieta, Pavel Drasar, José I. Miranda, Fernando P. Cossío*
Tetrahedron 2016, 72, 1120–1131.
(52) Synthesis of Chiral Spiro-nitroprolinates by Silver(I) Catalysis
Alberto Cayuelas, Ricardo Ortiz, Carmen Nájera, José M. Sansano,* Olatz Larrañaga, Abel de Cózar, Fernando P.
Cossío*
(51) New Insights into the Reactivity of Cisplatin with Free and Restrained Nucleophiles: Microsolvation
Effects and Base Selectivity in Cisplatin–DNA Interactions
Abel de Cózar, Olatz Larrañaga, F. Matthias Bickelhaupt, Eider San Sebastian, Elisabeth Ortega-Carrasco, Jean
-Didier Maréchal, Agustí Lledós, Fernando P. Cossío*
ChemPhysChem 2016, 17, 3932–3947.
(50) Enantioselective Synthesis of Polysubstituted Spiro-nitroprolinates Mediated by a
(R,R)‐Me-DuPhos·AgF-Catalyzed 1,3-Dipolar Cycloaddition
Alberto Cayuelas, Ricardo Ortiz, Carmen Nájera, José M. Sansano,* Olatz Larrañaga, Abel de Cózar, Fernando P.
Cossío*
Org. Lett. 2016, 18, 2926–2929.
(49) Ion-Pair SN2 Substitution: Activation Strain Analyses of Counter- Ion and Solvent Effects
Jalal Z. A. Laloo, Lydia Rhyman, Ponadurai Ramasami,* F. Matthias Bickelhaupt,* Abel de Cózar*
Chem. Eur. J. 2016, 22, 4431–4439.
(48) Alkenyl Arenes as Dipolarophiles in Catalytic Asymmetric 1,3-Dipolar Cycloaddition Reactions of
Azomethine Ylides
Ana Pascual Escudero, Abel de Cózar, Fernando P. Cossío,* Javier Adrio,* Juan C. Caretero*
Angew. Chem. Int. Ed. 2016, 55, 15334–15338.
(47) Donor-Stabilized 1,3-Disila-2,4-diazacyclobutadiene with a Nonbonded Si···Si Distance Compressed to a
Si=Si Double Bond Length
David Gau, Raphael Nougué, Nathalie Saffon-Merceron, Antoine Baceiredo, Abel de Cózar, Fernando P. Cossío,*
Daisuke Hashizume, Tsuyoshi Kato,*
2016
(60) Diastereoselective [3 + 2] vs [4 + 2] Cycloadditions of Nitroprolinates with α,β-Unsaturated Aldehydes and
Electrophilic Alkenes: An Example of Total Periselectivity
Verónica Selva, Olatz Larrañaga, Luis M. Castelló, Carmen Nájera, José M. Sansano,* Abel de Cózar*
J. Org. Chem. 2017, 82, 6298–6312.
(59) Asymmetric identity SN2 transition states: Nucleophilic substitution at carbon and silicon centers
Marucs V. J. Rocha, Nicole W. G. Smits, Lando P. Wolters, Abel de Cózar, Célia Fonseca Guerra, Teodorico C.
Ramalho, F. Matthias Bickelhaupt*
Int. J. Mass Spectros. 2017, 413, 85–91.
(58) Intramolecular SEAr Reactions of Phosphorus Compounds: Computational Approach to the Synthesis of
p-Extended Heterocycles
Olatz Larrañaga, Carlos Romero-Nieto,* Abel de Cózar*
Chem. Eur. J. 2017, 23, 17487–17496.
(57) Mono- and Di-Alkylation Processes of DNA Bases by Nitrogen Mustard Mechlorethamine
Olatz Larrañaga, Abel de Cózar,* Fernando P. Cossío
ChemPhysChem 2017, 17, 3390–3401.
(56) A Guide for the Design of Functional Polyaromatic Organophosphorus Materials
Philip Hindenberg, Alicia López-Andarias, Frank Rominger, Abel de Cózar,* Carlos Romero-Nieto*
Chem. Eur. J. 2017, 23, 13919–13928.
(55) Catalysis of a 1,3-dipolar reaction by distorted DNA incorporating a heterobimetallic platinum(II) and
copper(II) complex
Iván Rivilla, Abel de Cózar, Thomas Schäfer, Frank J. Hernandez, Alexander M. Bitner, Aitziber Eleta-Lopez, Ali
Aboudzadeh, José I. Santos, José I. Miranda, Fernando P. Cossío,*
(65) Alkaloids Reactivity: DFT Analysis of Selective Demethylation Reactions
Olatz Larrañaga, José I. Miranda, Fernando P. Cossío* Abel de Cózar*
J. Org. Chem. 2018, 83, 15105–15109.
(64) Unnatural Amino Acid Ester Catalyzed Formal Synthesis of (+)-Pancracine
María de G. Retamosa, Andrea Ruiz-Olalla, Tamra Bello, Abel de Cózar, Fernando P. Cossío*
(63) Cooperative Catalysis with Coupled Chiral Induction in 1,3-Dipolar Cycloadditions of Azomethine Ylides
Alberto Cayuelas, Olatz Larrañaga, Verónica Selva, Carmen Nájera,* Takahiko Akiyama, José M. Sansano,*
Abel de Cózar, José I. Miranda, Fernando P. Cossío*
Chem. Eur. J. 2018, 24, 8092–8097.
(62) Ion-Pair SN2 Reaction of OH– and CH3Cl: Activation Strain Analyses of Counterion and Solvent Effects
Jalal Z. A. Laloo, Lydia Rhyman, Olatz Larrañaga, Ponadurai Ramasami,* F. Matthias Bickelhaupt,* Abel de
Cózar*
Chem. Asian. J. 2018, 13, 1138–1147.
(61) A Three-component Enantioselective Cyclization Reaction Catalyzed by an Unnatural Amino Acid
Derivative
María de G. Retamosa, Andrea Ruiz-Olalla, Tamra Bello, Abel de Cózar, Fernando P. Cossío*
(70) Design, synthesis and amplified spontaneous emission of 1,2,5-benzothiadiazole derivatives
Raúl Martín,* Pilar Prieto,* José R. Carrillo, Ana M. Rodríguez, Abel de Cózar, Pedro C. Boj, María A.
Díaz-García, Manuel G Ramírez*
J. Mat. Chem. 2019, 7, 9996–10007.
(69) Switching Diastereoselectivity in Catalytic Enantioselective (3+2) Cycloadditions of Azomethine Ylides
Promoted by Metal Salts and Privileged Segphos-Derived Ligands
Guilherme S. Caleffi, Olatz Larrañaga, Marcos Ferrándiz-Saperas, Paulo R. R. Costa, Carmen Nájera,*
Abel de Cózar, Fernando P. Cossío,* José M. Sansáno*
J. Org. Chem. 2019, 84, 10593–10605.
(68) Dismantling the Hyperconjugation of p-Conjugated Phosphorus Heterocycles
Olatz Larrañaga, Carlos Romero-Nieto,* Abel de Cózar*
Chem. Eur. J. 2019, 25, 9035–9044.
(67) From bioactive pyrrolidino[3,4-c]pyrrolidines to more bioactive pyrrolidino[3,4-b]pyrrolidines via
ring-opening ring-closing promoted by sodium methoxide
Samet Belveren, Olatz Larrañaga, Samet Poyraz, H. Ali Dondas,* Mahmut Ülger, Ertan Sahin, Marcos
Ferrándiz-Saperas, José M. Sansano,* Abel de Cózar*
Synthesis 2019, 51, 1565–1577.
(66) Effect of an α-Methyl Substituent on the Dienophile on Diels-Alder endo:exo Selectivity
Olatz Larrañaga, Abel de Cózar*
2019
2017
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